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ACS Nano. 2016 Apr 26;10(4):4735-41. doi: 10.1021/acsnano.6b01233. Epub 2016 Mar 29.

Spontaneous, Straightforward Fabrication of Partially Reduced Graphene Oxide-Polypyrrole Composite Films for Versatile Actuators.

Author information

1
Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology , Beijing 100081, P. R. China.
2
Center of Advanced Science and Engineering for Carbon (Case4Carbon), Department of Macromolecular Science and Engineering, Case School of Engineering, Case Western Reserve University , Cleveland, Ohio 44106, United States.

Abstract

A facile one-step approach has been developed to fabricate partially reduced graphene oxide-polypyrrole (prGO-PPy) film via self-oxidation-reduction strategy, in which graphene oxide acts as the oxidant to polymerize pyrrole into PPy leading to the spontaneous partial reduction of GO and cross-linking between prGO and PPy via π-π interaction. With the convenient preparation method, a well controlled designed asymmetric actuator based on GO (or G)/prGO-PPy film with excellent humidity and electrochemical responses has been achieved for versatile stimulated actuations that will also play essential roles in advanced actuators for many important intelligent applications.

KEYWORDS:

actuator; film; graphene oxide; nanocomposites; polypyrrole

PMID:
27015325
DOI:
10.1021/acsnano.6b01233

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