K(+)-Induced in situ self-assembly of near-infrared luminescent membrane material armored with bigger Yb(III) complex crystallites

Wanmin Chen; Xiaoliang Tang; Wei Dou; Zhenghua Ju; Benhua Xu; Wenxuan Xu; Weisheng Liu

doi:10.1039/c6cc01938b

K(+)-Induced in situ self-assembly of near-infrared luminescent membrane material armored with bigger Yb(III) complex crystallites

Chem Commun (Camb). 2016 Apr 14;52(29):5124-7. doi: 10.1039/c6cc01938b. Epub 2016 Mar 18.

Authors

Wanmin Chen¹, Xiaoliang Tang, Wei Dou, Zhenghua Ju, Benhua Xu, Wenxuan Xu, Weisheng Liu

Affiliation

¹ Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province and State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Special Function Materials and Structure Design, Ministry of Education, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, 730000, China. tangxiaol@lzu.edu.cn liuws@lzu.edu.cn.

PMID: 26987655
DOI: 10.1039/c6cc01938b

Abstract

A semi-rigid ligand could capture effectively Yb(3+) ions to form a stable Yb(3+) complex and provide a potential cavity to accommodate alkali metal ions. Only K(+) ions could induce the Yb(3+) complex to form a 1D coordination polymer and promote the in situ formation of an NIR membrane coated with bigger Yb(3+) complex crystallites under mild conditions.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Cations / chemistry
Coordination Complexes / chemistry*
Crystallization
Ligands
Luminescence
Luminescent Agents / chemistry*
Membranes, Artificial*
Models, Molecular
Potassium / chemistry*
Spectroscopy, Near-Infrared
Ytterbium / chemistry*

Substances

Cations
Coordination Complexes
Ligands
Luminescent Agents
Membranes, Artificial
Ytterbium
Potassium