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Dalton Trans. 2016 Jan 28;45(4):1335-8. doi: 10.1039/c5dt04385a.

Homochiral and heterochiral Mn(II) coordination frameworks: spontaneous resolution dependent on dipyridyl ligands.

Author information

1
School of Chemistry and Molecular Engineering, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, Shanghai, People's Republic of China. qyue@chem.ecnu.edu.cn.

Abstract

An unsymmetric tetracarboxylic ligand collaborates with 4,4'-bipyridine to induce spontaneous resolution to form homochiral 3D coordination frameworks, while the use of longer dipyridyl ligands instead of 4,4'-bipyridine leads to isoreticular but heterochiral frameworks.

PMID:
26731285
DOI:
10.1039/c5dt04385a

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