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Dalton Trans. 2016 Jan 21;45(3):899-903. doi: 10.1039/c5dt04285b.

1,2,4-Diazaphospholide complexes of yttrium(iii), dysprosium(iii), erbium(iii), and europium(ii,iii): synthesis, X-ray structural characterization, and EPR analysis.

Author information

1
Institute of Organic Chemistry & College of Chemical and Materials Science, Shanxi Normal University, Gongyuan Street 1, Linfen, Shanxi Province 041004, China. wjzheng@sxnu.edu.cn wjzheng_sxnu@qq.com.
2
School of Chemistry and Chemical Engineering Central South University, Lushannan Road 932, Changsha, Hunan Province 410083, People's Republic of China.
3
Institute of Organic Chemistry & College of Chemical and Materials Science, Shanxi Normal University, Gongyuan Street 1, Linfen, Shanxi Province 041004, China. wjzheng@sxnu.edu.cn wjzheng_sxnu@qq.com and Key Laboratory of Magnetic Molecules and Magnetic Information Materials, Ministry of Education, Gongyuan Street 1, Linfen, Shanxi Province 041004, China.

Abstract

Several structurally characterized heteroleptic, charge-separated heterobimetallic, and polymeric alkali metal ate complexes of 1,2,4-diazaphospholide Y(iii), Dy(iii), Er(iii), Eu(iii), and Eu(ii) were prepared via the reaction of MCl3 and K[3,5-R2dp] in varied ratios at 200-220 °C (M = Y, Dy, Er, Eu; R = tBu, Ph).

PMID:
26666366
DOI:
10.1039/c5dt04285b

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