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Chem Commun (Camb). 2015 Nov 21;51(90):16255-8. doi: 10.1039/c5cc07010d.

Catalytic asymmetric sulfenylation to structurally diverse dithioketals.

Author information

1
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, 3663N, Zhongshan Road, Shanghai 200062, China.
2
Department of Chemistry, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China. fzhou@chem.ecnu.edu.cn and Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development, School of Chemistry and Chemical Engineering, East China Normal University, Shanghai, 200062, China.
3
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, 3663N, Zhongshan Road, Shanghai 200062, China and State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, CAS, Shanghai 200032, P. R. China.

Abstract

We report the first example of the highly enantioselective synthesis of structurally diverse chiral dithioketals via asymmetric sulfenylation of various types of S-based nucleophiles, catalyzed by a cheap cinchona alkaloid derivative, dihydroquinine.

PMID:
26399606
DOI:
10.1039/c5cc07010d
[Indexed for MEDLINE]

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