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Adv Mater. 2015 Aug 26;27(32):4775-80. doi: 10.1002/adma.201502418. Epub 2015 Jul 20.

Design of hydrophilic metal organic framework water adsorbents for heat reallocation.

Author information

1
Institut Lavoisier, UMR CNRS 8180, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035, Versailles Cedex, France.
2
Research Center for Nanocatalysts, Korea Research Institute of Chemical Technology (KRICT), Jang-Dong 100, Yuseong, Daejeon, 305-600, Republic of Korea.
3
Department of Chemistry, Center for Bioactive Molecular Hybrid, Yonsei University, Seodamoonku, Seoul, 120-749, Republic of Korea.
4
Institut Charles Gerhardt Montpellier, UMR CNRS 5253, Université Montpellier 2, 34095, Montpellier cedex 05, France.
5
Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel, Max-Eyth-Straße 2, 24118, Kiel, Germany.
6
Catalysis Engineering-Chemical Engineering Department, Delft University of Technology, Julianalaan, 136, 2628, BL Delft, The Netherlands.
7
Department of Chemistry, Sungkyunkwan University, Suwon, 440-476, Republic of Korea.

Abstract

A new hydrothermally stable Al polycarboxylate metal-organic framework (MOF) based on a heteroatom bio-derived aromatic spacer is designed through a template-free green synthesis process. It appears that in some test conditions this MOF outperforms the heat reallocation performances of commercial SAPO-34.

KEYWORDS:

aluminium carboxylate; heat transfer; metal-organic-frameworks; porosity; water sorption

PMID:
26193346
DOI:
10.1002/adma.201502418

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