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Chem Commun (Camb). 2015 Sep 14;51(71):13595-8. doi: 10.1039/c5cc04487a.

A facile solvent-free synthesis route for the assembly of a highly CO2 selective and H2S tolerant NiSIFSIX metal-organic framework.

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Functional Material Design, Discovery and Development (FMD3), Advanced Membrane & Porous Materials Center, 4700 King Abdullah University of Science and Technology, Thuwal 23955-6900, Kingdom of Saudi Arabia.


The development of materials for CO2 capture with high selectivity and high tolerance to H2S is of prime importance for various industrially relevant gas streams (e.g. natural gas and biogas upgrading as well as pre-combustion capture). Here, we report the successful fabrication of a MOF with combined exceptional CO2 capture properties and H2S tolerance, namely the NiSIFSIX-based MOF using both solvothermal and solvent-free methodologies.


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