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Chem Commun (Camb). 2015 Jul 25;51(58):11619-21. doi: 10.1039/c5cc03391h. Epub 2015 Jun 22.

Enhanced stability of Zr-doped Ba(CeTb)O(3-δ)-Ni cermet membrane for hydrogen separation.

Author information

1
Institute of Physical Chemistry and Electrochemistry, Leibniz University of Hannover, Callinstrasse 22, 30167 Hannover, Germany. yanying.wei@pci.uni-hannover.de.

Abstract

A mixed protonic and electronic conductor material BaCe(0.85)Tb(0.05)Zr(0.1)O(3-δ) (BCTZ) is prepared and a Ni-BCTZ cermet membrane is synthesized for hydrogen separation. Stable hydrogen permeation fluxes can be obtained for over 100 h through the Ni-BCTZ membrane in both dry and humid conditions, which exhibits an excellent stability compared with Ni-BaCe(0.95)Tb(0.05)O(3-δ) membrane due to the Zr doping.

PMID:
26097915
DOI:
10.1039/c5cc03391h

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