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Chem Commun (Camb). 2015 Jul 25;51(58):11576-9. doi: 10.1039/c5cc03151f. Epub 2015 Jun 22.

Azo-functionalized microporous organic polymers: synthesis and applications in CO2 capture and conversion.

Author information

1
Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. liuzm@iccas.ac.cn.

Abstract

Azo-functionalized MOPs (Azo-MOPs) were synthesized via oxidative polymerization of aromatic amines catalyzed by t-BuOCl/NaI (25 °C, 1 h, yield: >95%), which displayed an excellent coordinating ability with a Ru complex. The resulting Ru-coordinated Azo-MOPs displayed high CO2 capacity and high performances for catalyzing the methylation of amines with CO2 under low pressure (0.5 MPa).

PMID:
26097913
DOI:
10.1039/c5cc03151f

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