Tailoring Building Blocks and Their Boundary Interaction for the Creation of New, Potentially Superhard, Carbon Materials

Adv Mater. 2015 Jul 8;27(26):3962-8. doi: 10.1002/adma.201500188. Epub 2015 Jun 2.

Abstract

A strategy for preparing hybrid carbon structures with amorphous carbon clusters as hard building blocks by compressing a series of predesigned two-component fullerides is presented. In such constructed structures the building blocks and their boundaries can be tuned by changing the starting components, providing a way for the creation of new hard/superhard materials with desirable properties.

Keywords: amorphous carbon clusters; high hardness; high pressure; phase transitions; solvated fullerenes.