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J Colloid Interface Sci. 2015 Aug 1;451:212-5. doi: 10.1016/j.jcis.2015.03.044. Epub 2015 Apr 11.

Metal nanocrystal/metal-organic framework core/shell nanostructure from selective self-assembly induced by localization of metal ion precursors on nanocrystal surface.

Author information

1
Department of Nanobiochemistry, Frontiers of Innovative Research in Science and Technology (FIRST), Konan University, 7-1-20 Minatojimaminamimachi, Chuo-ku, Kobe 650-0047, Japan.
2
Department of Nanobiochemistry, Frontiers of Innovative Research in Science and Technology (FIRST), Konan University, 7-1-20 Minatojimaminamimachi, Chuo-ku, Kobe 650-0047, Japan. Electronic address: tsuruoka@center.konan-u.ac.jp.
3
Graduate School of Engineering, Kobe University, 1-1 Rokkodai, Nada-ku, Kobe 657-8501, Japan.
4
Department of Nanobiochemistry, Frontiers of Innovative Research in Science and Technology (FIRST), Konan University, 7-1-20 Minatojimaminamimachi, Chuo-ku, Kobe 650-0047, Japan. Electronic address: akamatsu@center.konan-u.ac.jp.

Abstract

Metal nanocrystal/metal-organic framework core/shell nanostructures have been constructed using metal ion-trapped nanocrystals as scaffolds through a selective self-assembly of framework components on the nanocrystal surfaces. The resulting nanostructures exhibit unique catalytic activity toward nitrophenol analogs.

KEYWORDS:

Core/shell structure; Metal nanocrystal; Metal–organic framework; Nanostructure

PMID:
25898115
DOI:
10.1016/j.jcis.2015.03.044

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