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Phys Rev Lett. 2015 Feb 27;114(8):085501. Epub 2015 Feb 27.

Wetting transition for carbon nanotube arrays under metal contacts.

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1
IBM T.J. Watson Research Center, Yorktown Heights, New York 10598, USA.

Abstract

Structural arrays with nanoscale spacing arise in many device concepts. Carbon nanotube transistors are an extreme example, where a practical technology will require arrays of parallel nanotubes with spacing of order 10 nm or less. We show that with decreasing pitch there is a first-order transition, from a robust structure in which the metal wets the substrate between tubes, to a poorly wetting structure in which the metal rides atop the nanotube array without touching the substrate. The latter is analogous to the superhydrophobic "lotus leaf effect." There is a sharp minimum in the delamination energy of metal contacts at the transition pitch. We discuss implications for contact resistance and possible mitigation strategies.

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