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J Am Chem Soc. 2015 Feb 4;137(4):1663-72. doi: 10.1021/ja5123528. Epub 2015 Jan 21.

Structure-assisted functional anchor implantation in robust metal-organic frameworks with ultralarge pores.

Author information

1
Department of Chemistry, Texas A&M University , College Station, Texas 77843-3255, United States.

Abstract

A facile functionalization assisted by the structural attributes of PCN-333 has been studied while maintaining the integrity of the parent MOF including ultralarge pores, chemical robustness, and crystallinity. Herein we thoroughly analyzed ligand exchange phenomena in PCN-333 and demonstrate that the extent of exchange can be tailored by varying the exchange conditions as potential applications may require. Through this method a variety of functional groups are incorporated into PCN-333. To further show the capabilities of this system introduction of a BODIPY fluorophore as a secondary functionality was performed to the functionalized framework via a click reaction. We anticipate the PCN-333 with functional anchor can serve as a stable platform for further chemistry to be explored in future applications.

PMID:
25581395
DOI:
10.1021/ja5123528
[Indexed for MEDLINE]

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