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Chem Commun (Camb). 2015 Feb 18;51(14):2859-62. doi: 10.1039/c4cc09679g.

Immobilization of Ag(i) into a metal-organic framework with -SO3H sites for highly selective olefin-paraffin separation at room temperature.

Author information

1
Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, P. R. China. baozb@zju.edu.cn.

Abstract

Introduction of Ag(i) ions into a sulfonic acid functionalized MOF ((Cr)-MIL-101-SO3H) significantly enhances its interactions with olefin double bonds, leading to its much higher selectivities for the separation of C2H4-C2H6 and C3H6-C3H8 at room temperature over the original (Cr)-MIL-101-SO3H and other adsorbents at room temperature.

PMID:
25581083
DOI:
10.1039/c4cc09679g
[Indexed for MEDLINE]

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