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Chem Commun (Camb). 2015 Feb 14;51(13):2679-82. doi: 10.1039/c4cc09428j.

A fluorescent heteroditopic hemicryptophane cage for the selective recognition of choline phosphate.

Author information

1
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai, 200062, P. R. China. ghgao@chem.ecnu.edu.cn.

Abstract

The first fluorescent hemicryptophane cage was synthesized and developed as an efficient and selective sensor for choline phosphate. The heteroditopic character of the host in the recognition process was evidenced. NMR experiments highlight a full encapsulation of the guest, inducing the chiralisation-like behavior of the achiral choline phosphate.

PMID:
25573628
DOI:
10.1039/c4cc09428j
[Indexed for MEDLINE]

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