Allyl sulphides in olefin metathesis: catalyst considerations and traceless promotion of ring-closing metathesis

Chem Commun (Camb). 2015 Jan 11;51(3):515-8. doi: 10.1039/c4cc07932a.

Abstract

Allyl sulphides are reactive substrates in ruthenium-catalysed olefin metathesis reactions, provided each substrate is matched with a suitable catalyst. A profile of catalyst activity is described, along with the first demonstration of allyl sulphides as traceless promoters in relayed ring-closing metathesis reactions.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkenes / chemistry*
  • Allyl Compounds / chemistry*
  • Catalysis
  • Cyclization
  • Magnetic Resonance Spectroscopy
  • Molecular Structure
  • Ruthenium / chemistry
  • Sulfides / chemistry*

Substances

  • Alkenes
  • Allyl Compounds
  • Sulfides
  • allyl sulfide
  • Ruthenium