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ACS Appl Mater Interfaces. 2014 Nov 26;6(22):20085-92. doi: 10.1021/am505677x. Epub 2014 Oct 21.

Reduced graphene oxide-silver nanoparticle composite as visible light photocatalyst for degradation of colorless endocrine disruptors.

Author information

1
Centre for Advanced Materials, Indian Association for the Cultivation of Science , Kolkata 700032, India.

Abstract

Sunlight-induced degradation of organic pollutants is an ideal approach for environmental pollution control and wastewater treatment. Although a variety of photocatalysts have been designed toward this goal, efficient degradation of colorless organic pollutants by visible light is a challenging issue. Here, we show that a reduced graphene oxide (rGO)-based composite with silver nanoparticle (rGO-Ag) can act as an efficient visible-light photocatalyst for the degradation of colorless organic pollutants. We have developed a simple, large-scale synthesis method for rGO-Ag and used it for the degradation of three well-known endocrine disruptors (phenol, bisphenol A, and atrazine) under UV and visible light. It is found that photocatalytic efficiency by rGO-Ag under visible light is significantly higher compared to that of rGO or silver nanoparticles. It is proposed that Ag nanoparticles offer visible-light-induced excitation of silver plasmons, and conductive rGO offers efficient charge separation and thus induces oxidative degradation of the organic pollutant. This approach can be extended for sunlight-induced degradation of different organic pollutants.

KEYWORDS:

endocrine disruptor; nanoparticle; photocatalysis; pollutant; reduced graphene oxide; surface plasmon

PMID:
25296393
DOI:
10.1021/am505677x
[Indexed for MEDLINE]

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