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Chem Pharm Bull (Tokyo). 2014;62(9):927-32.

α-Heteroarylation of ketones via the umpolung reaction of N-alkoxyenamine.

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1
Kobe Pharmaceutical University.

Abstract

A new method has been developed for the umpolung α-heteroarylation of ketones via an N-alkoxyenamine. The treatment of ketones with tris(heteroaryl)aluminum reagents in the presence of isoxazolidine gave the corresponding α-heteroarylated ketones in moderate to good yields.

PMID:
25177020
[Indexed for MEDLINE]
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