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Chem Commun (Camb). 2014 Sep 7;50(69):9827-30. doi: 10.1039/c4cc03725a.

Anion-induced dimerization of 5-fold symmetric cyanostars in 3D crystalline solids and 2D self-assembled crystals.

Author information

1
Department of Chemistry, Indiana University, 800 E. Kirkwood Ave., Bloomington, IN 47405, USA. tait@indiana.edu aflood@indiana.edu.

Abstract

Anions stabilize stacking of C5-symmetric macrocycles, called cyanostars, into dimers in solution and herein we demonstrate this stacking in solid-state crystals. We further show that this guest binding can be applied as a route to bilayer growth at the solution-graphite interface.

PMID:
25080328
DOI:
10.1039/c4cc03725a

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