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Sci Rep. 2014 Jul 22;4:5778. doi: 10.1038/srep05778.

Electrical conductivity of ice VII.

Author information

1
Institute for Solid State Physics, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581, Japan.
2
Computational Astrophysics Laboratory, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan.
3
1] Geodynamics Research Center, Ehime University, 2-5 Bunkyo-cho, Matsuyama, Ehime 790-8577, Japan [2] Institute for Solid State Physics, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581, Japan.
4
Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi 980-8577, Japan.

Abstract

It was discovered that a peak appears near a pressure of Pc = 10 GPa in the electrical conductivity of ice VII as measured through impedance spectroscopy in a diamond anvil cell (DAC) during the process of compression from 2 GPa to 40 GPa at room temperature. The activation energy for the conductivity measured in the cooling/heating process between 278 K and 303 K reached a minimum near Pc. Theoretical modelling and molecular dynamics simulations suggest that the origin of this unique peak is the transition of the major charge carriers from the rotational defects to the ionic defects.

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