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Chem Commun (Camb). 2014 Sep 11;50(70):10082-5. doi: 10.1039/c4cc04268a.

Organic-inorganic mixed-valence systems with strongly-coupled triarylamine and cyclometalated osmium.

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1
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China. zhongyuwu@iccas.ac.cn.

Abstract

Organic-inorganic mixed-valence systems with strongly-coupled triarylamine and cyclometalated osmium have been developed. They display two well-separated redox couples at low potentials. Each of the three readily accessible oxidation states can be distinguished by the absorbance at three different wavelengths.

PMID:
25046039
DOI:
10.1039/c4cc04268a
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