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Chem Commun (Camb). 2014 Sep 11;50(70):10059-61. doi: 10.1039/c4cc04227a.

Guest-induced supramolecular chirality in a ditopic azoprobe-cyclodextrin complex in water.

Author information

  • 1Department of Materials and Life Sciences, Sophia University, 7-1 Kioi-cho, Chiyoda-ku, Tokyo 102-8554, Japan. ta-hayas@sophia.ac.jp.

Abstract

We report a novel supramolecular chirality induced by the twisted structural change of two ditopic azoprobes (15C5-Azo-dpa) inside the chiral cavity of γ-cyclodextrin (γ-CyD) due to multi-point recognition of guest ions by 15C5-Azo-dpa molecules in water.

PMID:
25036024
DOI:
10.1039/c4cc04227a
[PubMed]
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