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Org Chem Front. 2014 Jul 1;1(5):468-472.

Vanadium-Catalyzed C(sp3)-H Fluorination Reactions.


Vanadium(III) oxide catalyzes the direct fluorination of C(sp3)-H groups with Selectfluor. This reaction is operationally simple. The catalyst and the reaction byproduct can be removed easily by filtration. Using this method, a fluorine atom can be introduced to the tertiary position of 1,4-cineole and L-menthone selectively.

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