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Nanoscale. 2014 Aug 7;6(15):8649-55. doi: 10.1039/c4nr02298j.

Transparent-conducting-oxide nanowire arrays for efficient photoelectrochemical energy conversion.

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1
Department of Material Science and Engineering, University of California at Berkeley, California 94709, USA. wook2@berkeley.edu.

Abstract

We report one dimensional (1-D) transparent-conducting-oxide arrays coated with light-absorbing semiconductors to simultaneously maximize light harvesting and charge collection in a photoelectrochemical (PEC) system. Tin-doped indium oxide (ITO) nanowire (NW) arrays are prepared on ITO thin-film substrates as the transparent-conducting-oxide, and TiO2 or CdSe/CdS/TiO2 thin layers were coated on the ITO NW arrays as the solar light-absorbing layers. The optimal PEC performance, 0.85% under 100 mW cm(-2) of light illumination, is obtained from ∼ 30 μm-long ITO NW, which is covered with ∼ 20 nm-thick TiO2 nanoshell. We finally demonstrate that the ITO NW-based photoelectrode is also compatible with one of the most efficient visible-light sensitizers, the CdS/CdSe quantum dot. Our approach using the transparent conducting 1-D array has wide potential to improve the PEC performances of conventional semiconducting materials through liberation from the poor charge transport.

PMID:
24942487
DOI:
10.1039/c4nr02298j
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