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Chem Commun (Camb). 2014 Jul 25;50(58):7870-3. doi: 10.1039/c4cc01631a.

Iron(III)-salan complexes catalysed highly enantioselective fluorination and hydroxylation of β-keto esters and N-Boc oxindoles.

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1
Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, 354 Feng Lin Road, Shanghai, China. xuzhenjiang@mail.sioc.ac.cn cmche@hku.hk.

Abstract

Chiral iron(iii)-salan complexes catalysed highly enantioselective α-fluorination and α-hydroxylation of β-keto esters and N-Boc oxindoles to give the corresponding products in high yields and good-to-excellent ee values under mild reaction conditions.

PMID:
24910967
DOI:
10.1039/c4cc01631a
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