The effect of varying structural modifications of carbon anodes, ranging from thin layers of crystalline boron-doped diamond up to highly graphitic bulk materials, was systematically examined for the possibility of electrochemical fixation and desorption of no-carrier-added [(18)F]fluoride from an aqueous solution. Pyrolysed carbon, i.e. "glassy carbon" (Sigradur(®)G), proved as the most efficient material for deposition and release. An overall radiochemical yield of about 60% was achieved when using this for fixation and DMSO/ionic additive as organic solution for the release of [(18)F]fluoride.
Keywords: Carbon electrodes; Electrodeposition; Intercalation; Micro fluidics; [(18)F]fluoride.
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