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Chemistry. 2014 Mar 10;20(11):3036-9.

Carbene-9-BBN ring expansions as a route to intramolecular frustrated Lewis pairs for CO2 reduction.

Abstract

Reactions of phosphine-derived carbenes with 9-borabicyclo[3.3.1]nonane (9-BBN) result in ring-expansion reactions to generate novel intramolecular frustrated Lewis pairs (FLPs). These FLPs effect the catalytic reduction of CO2 in the presence of boranes to give BOB and methoxy-borate species.

PMID:
24677611
DOI:
10.1002/chem.201304870
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