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Chem Commun (Camb). 2014 Apr 14;50(29):3882-4. doi: 10.1039/c4cc00809j. Epub 2014 Mar 4.

Synthesis of polycyclic substituted vinylarenes via a one-pot intramolecular aryl alkylation-N-tosylhydrazone insertion reaction.

Author information

1
State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China. liangym@lzu.edu.cn xupf@lzu.edu.cn.

Abstract

A novel method of a palladium-catalyzed/norbornene-mediated intramolecular C-H activation/N-tosylhydrazones insertion reaction is developed. In this process, various bicyclic or tricyclic substituted vinylarenes are obtained with high efficiency under mild conditions.

PMID:
24589628
DOI:
10.1039/c4cc00809j

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