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Acta Crystallogr C Struct Chem. 2014 Feb;70(Pt 2):178-81. doi: 10.1107/S2053229613034591. Epub 2014 Jan 11.

A two-dimensional bilayered Cd(II) coordination polymer with a three-dimensional supramolecular architecture incorporating 1,2-bis(pyridin-4-yl)ethene and 2,2'-(diazenediyl)dibenzoic acid.

Author information

1
College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, Henan, People's Republic of China.

Abstract

In poly[[μ2-1,2-bis(pyridin-4-yl)ethene-κ(2)N:N'][μ2-2,2'-(diazenediyl)dibenzoato-κ(3)O,O':O'']cadmium(II)], [Cd(C14H8N2O4)(C12H10N2)]n, the asymmetric unit contains one Cd(II) cation, one 2,2'-(diazenediyl)dibenzoate anion (denoted L(2-)) and one 1,2-bis(pyridin-4-yl)ethene ligand (denoted bpe). Each Cd(II) centre is six-coordinated by four O atoms of bridging/chelating carboxylate groups from three L(2-) ligands and by two N atoms from two bpe ligands, forming a distorted octahedron. The Cd(II) cations are bridged by L(2-) and bpe ligands to give a two-dimensional (4,4) layer. The layers are interlinked through bridging carboxylate O atoms from L(2-) ligands, generating a two-dimensional bilayered structure with a 3(6)4(13)6(2) topology. The bilayered structures are further extended to form a three-dimensional supramolecular architecture via a combination of hydrogen-bonding and aromatic stacking interactions.

KEYWORDS:

1,2-bis(pyridin-4-yl)ethene; 2,2′-(diazenediyl)dibenzoic acid; CdII coordination polymers; MOFs; crystal structure; metal–organic frameworks; two-dimensional bilayered structure

PMID:
24508964
DOI:
10.1107/S2053229613034591

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