Abstract
A simple and highly efficient synthetic strategy to access 3,3-bipyrrole derivatives by the reaction of dienone derivatives with TosMIC is reported. The reaction involves a van Leusen's pyrrole synthesis followed by an unusual C-C bond cleavage in the presence of water under mild conditions.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Carbon / chemistry*
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Cyanides / chemistry*
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Magnetic Resonance Spectroscopy
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Mass Spectrometry
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Pyrroles / chemistry*
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Spectrophotometry, Infrared
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Water / chemistry*
Substances
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Cyanides
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Pyrroles
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Water
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Carbon
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tosylmethyl isocyanide