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Angew Chem Int Ed Engl. 2014 Feb 17;53(8):2147-51. doi: 10.1002/anie.201308046. Epub 2014 Jan 21.

Using an organic molecule with low triplet energy as a host in a highly efficient blue electrophosphorescent device.

Author information

1
Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Hubei Key Lab on Organic and Polymeric Optoelectronic Materials, Department of Chemistry, Wuhan University, Wuhan, 430072 (P.R. China).

Abstract

To achieve high efficiencies in blue phosphorescent organic light-emitting diodes (PhOLEDs), the triplet energies (T1) of host materials are generally supposed to be higher than the blue phosphors. A small organic molecule with low singlet energy (S1) of 2.80 eV and triplet energy of 2.71 eV can be used as the host material for the blue phosphor, [bis(4,6-difluorophenylpyridinato-N,C(2'))iridium(III)] tetrakis(1-pyrazolyl)borate (FIr6; T1=2.73 eV). In both the photo- and electro-excited processes, the energy transfer from the host material to FIr6 was found to be efficient. In a three organic-layer device, the maximum current efficiency of 37 cd A(-1) and power efficiency of 40 Lm W(-1) were achieved for the FIr6-based blue PhOLEDs.

KEYWORDS:

blue phosphorescence; organic light-emitting diodes; triplet state

PMID:
24449253
DOI:
10.1002/anie.201308046
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