[Ag(70)(PW(9)O(34))(2)((t)BuC[triple bond, length as m-dash]C)(44)(H(2)O)(2)](8+): ionothermal synthesis of a silver cluster encapsulating lacunary polyoxometalate ions

Zhan-Guo Jiang; Kang Shi; Yu-Mei Lin; Quan-Ming Wang

doi:10.1039/c3cc49290g

[Ag(70)(PW(9)O(34))(2)((t)BuC[triple bond, length as m-dash]C)(44)(H(2)O)(2)](8+): ionothermal synthesis of a silver cluster encapsulating lacunary polyoxometalate ions

Chem Commun (Camb). 2014 Mar 4;50(18):2353-5. doi: 10.1039/c3cc49290g. Epub 2014 Jan 21.

Authors

Zhan-Guo Jiang¹, Kang Shi, Yu-Mei Lin, Quan-Ming Wang

Affiliation

¹ State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering Xiamen, 361005, P. R. China. linyum@xmu.edu.cn qmwang@xmu.edu.cn.

PMID: 24448207
DOI: 10.1039/c3cc49290g

Abstract

A silver alkynyl cluster containing a Ag70 shell and two lacunary [PW9O34](9-) templating ions was synthesized by an ionothermal approach. Fast core-shell electronic communication between silver(i) centers and polyoxometalates was verified via cyclic voltammetry studies in [BMIm]BF4.