Format

Send to

Choose Destination
Biomacromolecules. 2014 Mar 10;15(3):856-62. doi: 10.1021/bm401708m. Epub 2014 Jan 31.

Saponins: a renewable and biodegradable surfactant from its microwave-assisted extraction to the synthesis of monodisperse lattices.

Author information

1
IPREM, UMR 5254, CNRS/UPPA, 2 av.Angot, 64053 Pau cedex 9, France.

Abstract

Synthetic surfactants are widely used in emulsion polymerization, but it is increasingly desirable to replace them with naturally derived molecules with a reduced environmental burden. This study demonstrates the use of saponins as biodegradable and renewable surfactants for emulsion polymerization. This chemical has been extracted from soapnuts by microwave assisted extraction and characterized in terms of surfactant properties prior to emulsion polymerization. The results in terms of particle size distribution and morphology control have been compared to those obtained with classical nonionic (NP40) or anionic (SDS) industrial surfactants. Microwave-extracted saponins were able to lead to latexes as stable as standard PS latex, as shown by the CMC and CCC measurements. The saponin-stabilized PS particles have been characterized in terms of particle size and distribution by Dynamic Light Scattering and Asymmetrical Flow Field Flow Fractionation. Monomodal and monodispersed particles ranging from 250 to 480 nm in terms of diameter with a particle size distribution below 1.03 have been synthesized.

PMID:
24443771
DOI:
10.1021/bm401708m
[Indexed for MEDLINE]

Supplemental Content

Full text links

Icon for American Chemical Society
Loading ...
Support Center