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Acta Crystallogr Sect E Struct Rep Online. 2013 Aug 23;69(Pt 9):m520-1. doi: 10.1107/S1600536813022666. eCollection 2013.

Di-chlorido-[6,8,22,24,34,36-hexa-methyl-33,35-diaza-3,11,19,27-tetra-azonia-penta-cyclo[,9).1(13,17).1(21,25)]hexa-triaconta-1(33),5,7,9(34),13,15,17(35),21,23,25(36),29,31-dodeca-ene-κ(6) N (3),N (11),N (19),N (27),N (33),N (35)]dipalladium(II) bis(per-chlor-ate) N,N-di-methyl-formamide disolvate methanol disolvate.

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Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan.
Department of Chemistry, Graduate School of Science, Osaka University, Machikaneyama-cho, Toyonaka, Osaka 560-0043, Japan ; PRESTO, Japan Science and Technology Agency (JST), Japan.


In the crystal structure of the title compound, [Pd2(C36H42N6)Cl2](ClO4)2·2C3H7NO·2CH3OH, the dinuclear Pd(II) complex cation lies on an inversion center. Each Pd(II) ion has a distorted square-planar coordination sphere, defined by three N atoms of the macrocyclic ligand and a chloride ion. The Pd(II) complex cations and the methanol mol-ecules are linked through N-H⋯O and O-H⋯O hydrogen bonds, forming a zigzag chain along [101]. An intra-molecular N-H⋯Cl hydrogen bond is also observed.

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