Format

Send to

Choose Destination
Inorg Chem. 2014 Jan 21;53(2):667-9. doi: 10.1021/ic4021178. Epub 2013 Dec 27.

A novel heterometallic μ9-boride cluster: synthesis and structural characterization of [(η(5)-C5Me5Rh)2{Co6(CO)12}(μ-H)(BH)B].

Author information

1
Department of Chemistry, Indian Institute of Technology Madras , Chennai 600 036, India.

Abstract

The preparation, characterization, and electronic structure of the first heterometallic μ9-boride cluster [(Cp*Rh)2{Co6(CO)12}(μ-H)(BH)B)] has been reported. The interstitial boron atom in the title cluster is within the bonding contact of eight metal and one boron atom in a unique tricapped trigonal prism geometry.

PMID:
24372198
DOI:
10.1021/ic4021178

Supplemental Content

Full text links

Icon for American Chemical Society
Loading ...
Support Center