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Inorg Chem. 2014 Jan 21;53(2):852-60. doi: 10.1021/ic402193x. Epub 2013 Dec 23.

Efficient fluorinating agent through topochemical fluorination of Co-Fe layered double hydroxides.

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1
Clermont Université, Université Blaise Pascal , Institut de Chimie de Clermont-Ferrand, BP 10448, F-63000 Clermont-Ferrand, France.

Abstract

Mixed-metal inorganic fluoride, Co0.60Fe0.40F3, solid solutions are obtained through topochemical reactions of Co2FeCl(OH)6·2H2O LDH with molecular fluorine, F2, at temperatures as low as 100 °C. This solid solution possesses interesting F(•)-releasing ability, and its efficiency as a solid-state fluorinating agent is demonstrated on a commercial polyethylene film. (19)F solid state NMR and contact angle measurements underline the efficient fluorination of this polymer.

PMID:
24364744
DOI:
10.1021/ic402193x
[Indexed for MEDLINE]
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