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Dalton Trans. 2014 Feb 7;43(5):1970-3. doi: 10.1039/c3dt52999a.

Self-assembly of a [Ni8] carbonate cube incorporating four μ4-carbonato linkers through fixation of atmospheric CO2 by ligated [Ni2] complexes.

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  • 1Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302, India. dray@chem.iitkgp.ernet.in.

Abstract

The communication reports the synthesis, characterization, and magnetic behavior of a novel μ4-carbonato supported and imidazole capped ligated nickel cage [Ni8(μ-H2bpmp)4(μ4-CO3)4(ImH)8](NO3)4·2H2O (1) through self-assembly of ligand bound ferromagnetic Ni2 building blocks. Structural analysis indicates newer geometrical features for the coordination cage formation and dominant interdimer antiferromagnetic coupling resulting in a diamagnetic ground state.

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