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Chem Commun (Camb). 2014 Jan 25;50(7):808-10. doi: 10.1039/c3cc45286g.

Double γ-alkylation of allylic phosphorus ylides: a unique access to oxa-bicyclic[3.3.0] diene skeletons.

Author information

1
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China. tangy@sioc.ac.cn.

Abstract

A new ylide-initiated tandem cyclization reaction based on γ-dialkylation of allylic ylides has been realized, delivering a series of [3.3.0] oxa-bicyclic dienes in high yields with perfect diastereoselectivity.

PMID:
24292340
DOI:
10.1039/c3cc45286g

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