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Chem Commun (Camb). 2014 May 25;50(40):5376-8. doi: 10.1039/c3cc47445c. Epub 2013 Nov 28.

Oxidative C(sp3)-H bond cleavage, C-C and C=C coupling at a boron center with O2 as the oxidant mediated by platinum(II).

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1
Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, USA. avederni@umd.edu.

Abstract

Dimethyl- and diphenylplatinum(II) fragments Pt(II)R2 (R = Me, Ph) enable facile and efficient oxidative C(sp(3))-H bond cleavage and stepwise C-C and C=C coupling at the boron atom of a coordinated 1,5-cyclooctanediyldi(2-pyridyl)borato ligand with O2 as the sole oxidant.

PMID:
24287586
DOI:
10.1039/c3cc47445c
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