Format

Send to

Choose Destination
ACS Nano. 2013 Dec 23;7(12):11156-65. doi: 10.1021/nn4048759. Epub 2013 Dec 3.

Solution-based carbohydrate synthesis of individual solid, hollow, and porous carbon nanospheres using spray pyrolysis.

Author information

1
Materials Science and Engineering, School for Engineering of Matter, Transport and Energy, and ‡Department of Chemistry and Biochemistry, Arizona State University , Tempe, Arizona 85287, United States.

Abstract

A facile and scalable solution-based, spray pyrolysis synthesis technique was used to synthesize individual carbon nanospheres with specific surface area (SSA) up to 1106 m(2)/g using a novel metal-salt catalyzed reaction. The carbon nanosphere diameters were tunable from 10 nm to several micrometers by varying the precursor concentrations. Solid, hollow, and porous carbon nanospheres were achieved by simply varying the ratio of catalyst and carbon source without using any templates. These hollow carbon nanospheres showed adsorption of to 300 mg of dye per gram of carbon, which is more than 15 times higher than that observed for conventional carbon black particles. When evaluated as supercapacitor electrode materials, specific capacitances of up to 112 F/g at a current density of 0.1 A/g were observed, with no capacitance loss after 20,000 cycles.

PMID:
24274705
DOI:
10.1021/nn4048759
[Indexed for MEDLINE]

Supplemental Content

Full text links

Icon for American Chemical Society
Loading ...
Support Center