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Dalton Trans. 2014 Feb 7;43(5):1965-9. doi: 10.1039/c3dt52571f.

Emissive molecular nanomagnets: introducing optical properties in triangular oximato {Mn(III)3} SMMs from the deliberate replacement of simple carboxylate ligands with their fluorescent analogues.

Author information

1
Department of Chemistry, 500 Glenridge Ave, Brock University, L2S 3A1 St. Catharines, Ontario, Canada. tstamatatos@brocku.ca.

Abstract

The targeted replacement of acetate groups in the optically inactive [Mn(III)3O(O2CMe)3(mpko)3](ClO4) single-molecule magnet with their naphthalene, anthracene, and pyrene fluorescent analogues has led to three new emissive SMMs with enhanced photoluminescence properties and potential applications in the field of molecular electronics.

PMID:
24270941
DOI:
10.1039/c3dt52571f
[Indexed for MEDLINE]

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