Format

Send to

Choose Destination
See comment in PubMed Commons below
Sci Rep. 2013 Nov 18;3:3234. doi: 10.1038/srep03234.

Durability enhancement of intermetallics electrocatalysts via N-anchor effect for fuel cells.

Author information

1
R&D Centre for Vehicle Battery and Energy Storage, General Research Institute for Nonferrous Metals, Beijing 100088, China.

Abstract

Insufficient durability and catalytic activity of oxygen reduction reaction (ORR) electrocatalyst are key issues that have to be solved for the practical application of low temperature fuel cell. This paper introduces a new catalyst design strategy using N-anchor to promote the corrosion resistance of electrocatalyst. The as-synthesized N-Pt3Fe1/C shows a high electrocatalytic activity and a superior durability towards ORR. The kinetic current density of N-Pt3Fe1/C as normalized by ECSA is still as high as 0.145 mA cm(-2) and only 7% loss after 20,000 potential cycles from 0.6 to 1.2 V (vs. NHE) in O2-bubbling perchloric acid solution, whereas Pt3Fe1/C shows 49% loss under the same tests. The N-anchor approach offers novel opportunities for the development of ORR catalyst with excellent electrochemical properties.

PubMed Commons home

PubMed Commons

0 comments
How to join PubMed Commons

    Supplemental Content

    Full text links

    Icon for Nature Publishing Group Icon for PubMed Central
    Loading ...
    Support Center