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Chem Commun (Camb). 2013 Dec 25;49(99):11662-4. doi: 10.1039/c3cc46778c.

Synthesis of α,β-unsaturated carbonyl compounds via a visible-light-promoted organocatalytic aerobic oxidation.

Author information

1
Key Laboratory of Chemical Genomics, School of Chemical Biology and Biotechnology, Peking University, Shenzhen Graduate School, Shenzhen, 518055, China.

Abstract

α,β-Unsaturated ketones and aldehydes have been synthesized from their corresponding silyl enol ethers in a straightforward protocol involving a visible-light promoted organocatalytic, aerobic oxidation reaction. A cheap organic dye was used catalytically in these reactions as the photosensitizer.

PMID:
24190501
DOI:
10.1039/c3cc46778c
[Indexed for MEDLINE]

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