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Org Lett. 2013 Oct 18;15(20):5362-5. doi: 10.1021/ol402672e. Epub 2013 Oct 7.

Nickel-catalyzed C-P cross-coupling of arylboronic acids with P(O)H compounds.

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1
Department of Chemistry and Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, Fujian, China.

Abstract

A novel and efficient Ni-catalyzed coupling of a wide range of arylboronic acids with H-phosphites, H-phosphinate esters, and H-phosphine oxides has been developed, providing a general and powerful tool for the synthesis of various aryl-phosphorus compounds, especially for valuable triarylphosphine oxides, in good to excellent yield. This protocol is the first Ni-catalyzed C-P bond-forming reaction between arylboronic acids and P(O)H compounds.

PMID:
24099283
DOI:
10.1021/ol402672e
[Indexed for MEDLINE]
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