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Acta Crystallogr Sect E Struct Rep Online. 2013 Sep 12;69(Pt 10):m541. doi: 10.1107/S1600536813024045. eCollection 2013.

Poly[tetra-methyl-ammonium [tri-μ2-formato-κ(6) O:O'-manganate(II)]].

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School of Chemistry and Material Science, Shanxi Normal University, Linfen 041004, People's Republic of China.


In the title compound, {(C4H12N)[Mn(HCO2)3]} n , the Mn(II) atom lies on an inversion centre and is coordinated by O-atom donors from the three double-bridging formate ligands, one of which lies across a crystallographic mirror plane, giving a slightly distorted octahedral coordination sphere. A three-dimensional NaCl-type framework is generated in which the tetra-methyl-ammonium cations, which lie across mirror planes and occupy the cavities in the polymer structure, form weak C-H⋯O hydrogen bonds with the formate ligands.

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