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Org Lett. 2013 Oct 18;15(20):5358-61. doi: 10.1021/ol402644y. Epub 2013 Oct 2.

Tandem isomerization and C-H activation: regioselective hydroheteroarylation of allylarenes.

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  • 1Institute of Chemistry, Academia Sinica , Nangang, Taipei, Taiwan, Republic of China , and Department of Applied Chemistry, National Chiao Tung University , Hsinchu, Taiwan, Republic of China.

Abstract

The first Ni-promoted prototype reaction based on the tandem C-H activation of heteroarenes with alkene isomerization is demonstrated, leading to the branched hydroheteroarylation products. Simultaneously, the reaction selectivity can be chemically switched to linear adducts through Ni-Al tandem catalysis.

PMID:
24087858
DOI:
10.1021/ol402644y
[PubMed]
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