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ACS Nano. 2013 Oct 22;7(10):9325-35. doi: 10.1021/nn404015y. Epub 2013 Sep 24.

Realizing high-efficiency omnidirectional n-type Si solar cells via the hierarchical architecture concept with radial junctions.

Author information

1
Institute of Photonics and Optoelectronics & Department of Electrical Engineering, National Taiwan University , Taipei 10617, Taiwan.

Abstract

Hierarchical structures combining micropyramids and nanowires with appropriate control of surface carrier recombination represent a class of architectures for radial p-n junction solar cells that synergizes the advantageous features including excellent broad-band, omnidirectional light-harvesting and efficient separation/collection of photoexcited carriers. The heterojunction solar cells fabricated with hierarchical structures exhibit the efficiency of 15.14% using cost-effective as-cut Czochralski n-type Si substrates, which is the highest reported efficiency among all n-type Si nanostructured solar cells. We also demonstrate the omnidirectional solar cell that exhibits the daily generated power enhancement of 44.2% by using hierarchical structures, as compared to conventional micropyramid control cells. The concurrent improvement in optical and electrical properties for realizing high-efficiency omnidirectional solar cells using as-cut Czochralski n-type Si substrates demonstrated here makes a hierarchical architecture concept promising for large-area and cost-effective mass production.

PMID:
24047200
DOI:
10.1021/nn404015y

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