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Chem Commun (Camb). 2013 Oct 28;49(84):9809-11. doi: 10.1039/c3cc44745f.

Pillar substitution modulates CO2 affinity in "mmo" topology networks.

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1
Department of Chemistry, CHE205, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620, USA. xtal@usf.edu.

Abstract

The use of WO4(2-) instead of CrO4(2-) or MoO4(2-) as an angular pillar in topology nets has afforded two isostructural porous nets of formula [M(bpe)2WO4] (M = Co or Ni, bpe = 1,2-(4-pyridyl)ethene). The Ni variant, WOFOUR-1-Ni, is highly selective towards CO2 thanks to its exceptionally high isosteric heat of adsorption (Qst) of -65.5 kJ mol(-1) at zero loading.

PMID:
24029926
DOI:
10.1039/c3cc44745f
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