Format

Send to

Choose Destination
See comment in PubMed Commons below
Org Lett. 2013 Sep 20;15(18):4818-21. doi: 10.1021/ol402213k. Epub 2013 Sep 6.

Free-radical variant for the synthesis of functionalized 1,5-diketones.

Author information

1
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University , Singapore 637371, Singapore, and Laboratoire de Synth├Ęse Organique, CNRS UMR 7652 Ecole Polytechnique , 91128 Palaiseau Cedex, France.

Abstract

A free-radical approach for the synthesis of functionalized 1,5-diketones has been accomplished through an effective combination play between alkenylacylphosphonates and keto-xanthates as radical surrogates of enolates and enones, respectively.

PMID:
24011200
DOI:
10.1021/ol402213k
[Indexed for MEDLINE]
PubMed Commons home

PubMed Commons

0 comments
How to join PubMed Commons

    Supplemental Content

    Full text links

    Icon for American Chemical Society
    Loading ...
    Support Center