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Chem Commun (Camb). 2013 Oct 14;49(80):9182-4. doi: 10.1039/c3cc45587d. Epub 2013 Aug 29.

Reversible supra-channel effects: 3D kagome structure and catalysis via a molecular array of 1D coordination polymers.

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1
Department of Chemistry, Pusan National University, Pusan 609-735, Korea. oksjung@pusan.ac.kr.

Abstract

Self-assembly of CuX2 (X(-) = ClO4(-) and BF4(-)) with 2,3-bis(nicotinoyloxy)naphthalene yields a 1D loop-chain skeleton. The loop-chains form an ensemble constituting a unique 3D kagome-type structure with both hexagonal and trigonal supra-channels. The unprecedented supra-channel effects on the catalytic oxidation of 3,5-di-tert-butylcatechol to 3,5-di-tert-butylbenzoquinone were investigated.

PMID:
23989602
DOI:
10.1039/c3cc45587d
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